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- W2081857980 abstract "The distonic radical ion ·CH2CH2SCH+2 (1+·), generated by dissociative electron ionization of 1,4-dithiane or 1,4-thioxane, is identified in the gas phase by its collisionally activated dissociation (CAD), neutralization-reionization (+NR+) and charge-reversal (+CR−) mass spectra. The unimolecular chemistry of 1+· is shown to be substantially different from that of the isomeric, ring-closed, trimethylene sulfide ion (2+·). Hence, a substantial isomerization barrier must separate 1+· from the thermodynamically more stable 2+·. Charge permutation (i.e. charge-stripping, +NR+ and +CR−) are far superior, compared to collision-induced fragmentation, for distinguishing 1+· from 2+·, mainly because the oxidized (1++ and 2++) and reduced forms (1 and 2 as well as 1−· and 2−·) of these cations have much lower tendencies for isomerization than 1+· and 2+· themselves. The diradical ·CH2CH2SCH" @default.
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- W2081857980 date "1996-01-31" @default.
- W2081857980 modified "2023-10-17" @default.
- W2081857980 title "Distonic Ion·CH2CH2SCH+2 and the Isomeric Trimethylene and Propylene Sulfide Radical Cations. Assessment of Structures and Reactivities via Decomposition and Redox Reactions" @default.
- W2081857980 doi "https://doi.org/10.1002/(sici)1097-0231(19960131)10:2<235::aid-rcm472>3.0.co;2-1" @default.
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