Matches in SemOpenAlex for { <https://semopenalex.org/work/W2081874282> ?p ?o ?g. }
Showing items 1 to 93 of
93
with 100 items per page.
- W2081874282 endingPage "2196" @default.
- W2081874282 startingPage "2191" @default.
- W2081874282 abstract "Structural and electronic transitions in poly(phenylenesulfide phenyleneamine) (PPSA) upon electrochemical doping have been investigated. The results indicate that polarons are the predominant charge defects at low doping levels, yielding an electronically and mechanically stable material. The electrochemical doping at high potentials induces a transition of the polarons to a bipolaron state. Due to the heterogeneous nature of the polymer chain and different oxidation potentials associated with aniline and phenylene sulfide units, the formation of polaron and bipolaron is distinguished as two separated steps. The dopant perchlorate ion exists in the polymer matrix, not only as charge neutralizer but also as a ligand that is simultaneously Coulombically bound to the positively charged S or N sites on one polymer chain and hydrogen bonded to the N−H group on the neighboring chain. The formation of such perchlorate anion centered Coulombic/hydrogen-bonded complexes has a major impact on the electrochemical activity and the morphology of the doped polymer. Also due to stabilization of the dopant ions, the doped polymer can be retained in a stable and desirable oxidation state." @default.
- W2081874282 created "2016-06-24" @default.
- W2081874282 creator A5014708917 @default.
- W2081874282 creator A5015995069 @default.
- W2081874282 creator A5063217972 @default.
- W2081874282 creator A5072097825 @default.
- W2081874282 date "2001-02-21" @default.
- W2081874282 modified "2023-09-27" @default.
- W2081874282 title "Structural, Electronic, and Morphological Changes in Poly(phenylenesulfide phenyleneamine) upon Electrochemical Doping" @default.
- W2081874282 cites W1984817522 @default.
- W2081874282 cites W2004515385 @default.
- W2081874282 cites W2022639040 @default.
- W2081874282 cites W2048290861 @default.
- W2081874282 cites W2053170651 @default.
- W2081874282 cites W2072231531 @default.
- W2081874282 cites W2087716089 @default.
- W2081874282 cites W2160893458 @default.
- W2081874282 cites W2080674036 @default.
- W2081874282 doi "https://doi.org/10.1021/jp004005u" @default.
- W2081874282 hasPublicationYear "2001" @default.
- W2081874282 type Work @default.
- W2081874282 sameAs 2081874282 @default.
- W2081874282 citedByCount "17" @default.
- W2081874282 countsByYear W20818742822015 @default.
- W2081874282 countsByYear W20818742822020 @default.
- W2081874282 crossrefType "journal-article" @default.
- W2081874282 hasAuthorship W2081874282A5014708917 @default.
- W2081874282 hasAuthorship W2081874282A5015995069 @default.
- W2081874282 hasAuthorship W2081874282A5063217972 @default.
- W2081874282 hasAuthorship W2081874282A5072097825 @default.
- W2081874282 hasConcept C121332964 @default.
- W2081874282 hasConcept C145148216 @default.
- W2081874282 hasConcept C147120987 @default.
- W2081874282 hasConcept C147789679 @default.
- W2081874282 hasConcept C159467904 @default.
- W2081874282 hasConcept C159985019 @default.
- W2081874282 hasConcept C17525397 @default.
- W2081874282 hasConcept C178790620 @default.
- W2081874282 hasConcept C179104552 @default.
- W2081874282 hasConcept C185592680 @default.
- W2081874282 hasConcept C188027245 @default.
- W2081874282 hasConcept C191952053 @default.
- W2081874282 hasConcept C192562407 @default.
- W2081874282 hasConcept C2780709120 @default.
- W2081874282 hasConcept C2781436544 @default.
- W2081874282 hasConcept C49040817 @default.
- W2081874282 hasConcept C521977710 @default.
- W2081874282 hasConcept C52859227 @default.
- W2081874282 hasConcept C57863236 @default.
- W2081874282 hasConcept C62520636 @default.
- W2081874282 hasConcept C64127065 @default.
- W2081874282 hasConceptScore W2081874282C121332964 @default.
- W2081874282 hasConceptScore W2081874282C145148216 @default.
- W2081874282 hasConceptScore W2081874282C147120987 @default.
- W2081874282 hasConceptScore W2081874282C147789679 @default.
- W2081874282 hasConceptScore W2081874282C159467904 @default.
- W2081874282 hasConceptScore W2081874282C159985019 @default.
- W2081874282 hasConceptScore W2081874282C17525397 @default.
- W2081874282 hasConceptScore W2081874282C178790620 @default.
- W2081874282 hasConceptScore W2081874282C179104552 @default.
- W2081874282 hasConceptScore W2081874282C185592680 @default.
- W2081874282 hasConceptScore W2081874282C188027245 @default.
- W2081874282 hasConceptScore W2081874282C191952053 @default.
- W2081874282 hasConceptScore W2081874282C192562407 @default.
- W2081874282 hasConceptScore W2081874282C2780709120 @default.
- W2081874282 hasConceptScore W2081874282C2781436544 @default.
- W2081874282 hasConceptScore W2081874282C49040817 @default.
- W2081874282 hasConceptScore W2081874282C521977710 @default.
- W2081874282 hasConceptScore W2081874282C52859227 @default.
- W2081874282 hasConceptScore W2081874282C57863236 @default.
- W2081874282 hasConceptScore W2081874282C62520636 @default.
- W2081874282 hasConceptScore W2081874282C64127065 @default.
- W2081874282 hasIssue "11" @default.
- W2081874282 hasLocation W20818742821 @default.
- W2081874282 hasOpenAccess W2081874282 @default.
- W2081874282 hasPrimaryLocation W20818742821 @default.
- W2081874282 hasRelatedWork W1973803474 @default.
- W2081874282 hasRelatedWork W2013692982 @default.
- W2081874282 hasRelatedWork W2053105088 @default.
- W2081874282 hasRelatedWork W2060600392 @default.
- W2081874282 hasRelatedWork W2081874282 @default.
- W2081874282 hasRelatedWork W2105359895 @default.
- W2081874282 hasRelatedWork W2377663317 @default.
- W2081874282 hasRelatedWork W2918121100 @default.
- W2081874282 hasRelatedWork W4233896862 @default.
- W2081874282 hasRelatedWork W4298130298 @default.
- W2081874282 hasVolume "105" @default.
- W2081874282 isParatext "false" @default.
- W2081874282 isRetracted "false" @default.
- W2081874282 magId "2081874282" @default.
- W2081874282 workType "article" @default.