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• W2081894152 abstract "Binding of pyrene, fluoranthene, and phenanthrene to dissolved humic acids (HA) was determined by the fluorescence quenching (FQ) and complexation-flocculation (CF) methods. Determinations by the CF method, using varying contaminant concentrations and a constant HA concentration, yielded nonlinear Freundlich-type isotherms (n = 0.65-0.84). Experiments using both the CF and the FQ methods with varying HA concentrations and a constant contaminant concentration yielded curved Stern-Volmer-type plots that also indicate nonlinear binding. These findings suggest that linear partitioning or site complexation in the presence of excess available sites cannot fully describe the interactions of hydrophobic compounds with dissolved humic material. Site-specific hydrophobic interactions at limited interior or external molecular surfaces may be considered." @default.
• W2081894152 created "2016-06-24" @default.
• W2081894152 creator A5006247073 @default.
• W2081894152 creator A5042112346 @default.
• W2081894152 date "2002-01-26" @default.
• W2081894152 modified "2023-10-14" @default.
• W2081894152 title "Evidence for Nonlinear Binding of PAHs to Dissolved Humic Acids" @default.
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• W2081894152 doi "https://doi.org/10.1021/es001996g" @default.
• W2081894152 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/11918025" @default.
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