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- W2081900669 abstract "In this study, the electrical properties of carbon nanotubes (CNTs) assembled into different architectures using the layer-by-layer technique have been investigated. The CNTs were modified with either anionic water-soluble polyaniline blend poly(sodium 4-styrenesulfonate) (PANI-PSS) or cationic poly(diallydimethyl ammonium chloride) (PDADMAC) to form negatively charged CNT− and positively charged CNT+. PANI-PSS was synthesized by interfacial polymerization of aniline using PSS as template. The first of the three architectures studied was assembled by the LbL deposition of anionic CNT− and cationic CNT+ while the two others were prepared by the deposition of only 1 type of CNTs (CNT+ or CNT−) with an oppositely charged polyelectrolyte to form PDADMAC/CNT− and PANI-PSS/CNT+. The thickness and surface roughness of the three different films were characterized by atomic force microscopy (AFM) while the electrical and optical properties were measured using a four points probe setup and a UV–vis spectrophotometer, respectively. The dispersion of the CNTs using PANI-PSS as capping agent was the least efficient when compared to the PDADMAC leading to a lower adsorption on a charged substrate. Interestingly, the layer-by-layer deposition of the CNT−/CNT+ films had a slower growth but displayed a superior electrical conductivity when compared to the other two architectures." @default.
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- W2081900669 date "2014-03-01" @default.
- W2081900669 modified "2023-09-25" @default.
- W2081900669 title "Layer-by-layer deposition of cationic and anionic carbon nanotubes into thin films with improved electrical properties" @default.
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- W2081900669 doi "https://doi.org/10.1016/j.colsurfa.2013.12.040" @default.
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