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• W2081906481 abstract "Vertically aligned polyaniline (PANI) structures were prepared by controlling the deposition current density during a stepwise template-free electrochemical deposition process of aniline on a glassy carbon electrode (GCE). Scanning electron micrographs (SEMs) showed the formation of cauliflower PANI structures, each with a diameter of approximately 2–3 and 10 μm in length. The cauliflower-like PANI electrode was modified with multiwalled carbon nanotubes (cauliflower PANI/MWCNTs) and used as the working electrode for electrochemical detections where H 2 O 2 and glucose were used as the models for the chemical sensor and biosensor, respectively. The sensor provided linearity in the range of 1.0 to 150 μM of H 2 O 2 with the limit of detection (LOD) of 50 nM. This is 100-fold better than the LOD of the bare GCE. Moreover, this sensor exhibited remarkable operational stability, i.e., 50 μM H 2 O 2 could be analyzed up to 140 times with a 2.7 % relative standard deviation (RSD). A glucose biosensor was prepared using the modified cauliflower PANI/MWCNT electrode. This had a 3.4 times higher sensitivity than an electrode modified with PANI film/MWCNTs. The regular size and high surface-to-volume ratio of the cauliflower PANI electrode will provide good opportunities for further biosensor applications." @default.
• W2081906481 created "2016-06-24" @default.
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• W2081906481 date "2012-04-07" @default.
• W2081906481 modified "2023-10-18" @default.
• W2081906481 title "Cauliflower polyaniline/multiwalled carbon nanotube electrode and its applications to hydrogen peroxide and glucose detection*" @default.
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• W2081906481 doi "https://doi.org/10.1351/pac-con-11-10-07" @default.
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