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- W2081917547 abstract "Abstract The present paper presents a new method to build up temperature‐responsive surfaces. First a poly(silsesquioxane)‐block‐poly(N‐isopropyl‐acrylamide) (PMSSQ‐ b ‐PNIPAM) was successfully synthesized using RAFT polymerization. Spin‐coating or dip‐coating of PMSSQ‐ b ‐PNIPAM onto glass surfaces resulted in temperature‐responsive surfaces. Surface ATR FT‐IR measurements proofed the successful surface modification using PMSSQ‐ b ‐PNIPAM. IR fine structures of PNIPAM and PMSSQ could be assigned, respectively. In capillary rise experiments a change of the meniscus height measured at temperatures below or above LCST was observed, indicating a different wetting behavior. Thus, a simple spin‐ or dip‐coating step results in a clean and temperature‐responsive surface." @default.
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- W2081917547 date "2007-03-28" @default.
- W2081917547 modified "2023-10-16" @default.
- W2081917547 title "Temperature-Responsive Surface Coatings Based on Poly(methylsilsesquioxane)-hybrid Polymers" @default.
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- W2081917547 doi "https://doi.org/10.1002/masy.200750414" @default.
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