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- W2081918274 abstract "Complexation between terbium(III) and (−)-quinic acid (quin) (1,2,3,5-tetrahydroxycyclohexanecarboxylic acid) was studied by means of circularly polarized luminescence spectroscopy. [Tb]:[quin] ratios of 1:1, 1:2, 1:3, 1:5 and 1:10 were studied, and measurements of intermolecular energy transfer were used to determine pH regions in which the complexes remained monomeric. Simplification of the solution phase equilibria was sought by studying the behavior of mixed ligand complexes. The compounds contained terbium(III), quin and a second achiral ligand (ethylenediaminetetraacetic acid, 1,2-cyclohexanediaminetetraacetic acid, pyridine-2,6-dicarboxylic acid or 5-sulfosalicylic acid). The chiroptical studies permitted certain conclusions to be drawn regarding the nature of the bonding existing between the terbium(III) ion and the quin ligand." @default.
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- W2081918274 date "1981-01-01" @default.
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- W2081918274 title "Vicinal effects observed in the circularly polarized luminescence spectra of mixed-ligand Tb(III) complexes" @default.
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- W2081918274 doi "https://doi.org/10.1016/s0020-1693(00)84723-4" @default.
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