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• W2081921613 abstract "Abstract Three new coordination complexes [Mn(L)(H 2 O) 2 ](1,4-BDC)·2H 2 O ( 1 ), [Mn(L) 0.5 (1,4-BDC)]CH 3 OH·H 2 O ( 2 ) and [Mn(L)(H 2 O) 2 ](1,2-HBDC) 2 ·2H 2 O ( 3 ) were synthesized by solvothermal reactions of 1,2,4,5-tetrakis(imidazol-1-ylmethyl)benzene (L) and 1,4-benzenedicarboxylic acid (1,4-H 2 BDC) or 1,2-benzenedicarboxylic acid (1,2-H 2 BDC) with Mn(II) salt, and characterized by single crystal X-ray diffraction, IR, thermogravimetric and elemental analyses. In complexes 1 and 3 , each ligand L links four Mn(II) atoms to form two-dimensional (2D) cationic network with non-coordinated 1,4-BDC 2− and 1,2-HBDC − anions lying in the voids between the two adjacent layers, respectively. The 2D layers are further connected together by hydrogen bonds to give three-dimensional (3D) supramolecular structures. However, the 1,4-BDC 2− in 2 acts not only as counteranion, but also as bridging ligand leading to the formation of 2-fold interpenetrated 3D framework with pcu (primitive cubic unit) topology. The Mn(II) atoms bridged by carboxylate groups in 2 show antiferromagnetic interactions." @default.
• W2081921613 created "2016-06-24" @default.
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• W2081921613 date "2010-10-01" @default.
• W2081921613 modified "2023-09-23" @default.
• W2081921613 title "Synthesis, structure and property of manganese(II) complexes with mixed tetradentate imidazole-containing ligand and benzenedicarboxylate" @default.
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• W2081921613 doi "https://doi.org/10.1016/j.ica.2010.07.012" @default.
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