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- W2081937405 abstract "The condensations of ribonucleoside 3′-H-phosphonates with simple alcohols and nucleosides are known to be stereoselective reactions that favour formation of DP(SP)-diastereomers of the produced H-phosphonate diesters without engaging any chiral auxiliaries. We have investigated various reaction conditions in order to attain the highest stereoselectivity for the condensation. With an optimal choice of solvents, reagent concentrations, temperature and the condensing agent used, the diastereomeric excess of the DP(SP)-isomers of dinucleoside H-phosphonates was enhanced from the initial 50–70% to ca. 85%." @default.
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- W2081937405 date "1993-06-01" @default.
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- W2081937405 title "Stereocontrolled Synthesis of P-Chiral Analogues of Oligonucleotides" @default.
- W2081937405 doi "https://doi.org/10.1006/bioo.1993.1014" @default.
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