FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2081982108> ?p ?o ?g. }

• W2081982108 endingPage "60" @default.
• W2081982108 startingPage "47" @default.
• W2081982108 abstract "A new arrangement of a flow-through polarographic detector has been designed with a rapidly dropping mercury electrode. The detector is especially usefull for reversed-phase high-performance liquid chromatography (HPLC). It has been shown that the properties of the detector are similar to those of a UV detector operated at 254 nm. An electroactive substance in the eluate can be determined at flow-rates not exceeding 6 ml min−1. An upwards direction of flow of the solution facilitates the automatic removal of gas bubbles, which are swept to the detector with the column effluent. The volume of solution necessary to wash out 95% of the detection passage filled with another solution is about 0.1 ml, which is approximately equal to the volume when using a UV (254 nm) detector with a geometrical volume of the detection passage of 8 μl. The detector sensitivity with injection of cadmium nitrate solution is (3.6 ± 0.4)·10−4 A 1 mol−1, and the linear dynamic range is 5·10−4–5·10−2M cadmium nitrate with 5-μl injections. The selection of a suitably short drop time at a given flow-rate enables one to eliminate current signal disturbances on the recorded curves. Thus the current is diffusion or convective-diffusion controlled, irrespective of the presence or absence of turbulence. The application of the detector to HPLC is illustrated with the separation of a mixture of testosteroids." @default.
• W2081982108 created "2016-06-24" @default.
• W2081982108 creator A5035615805 @default.
• W2081982108 creator A5041428842 @default.
• W2081982108 creator A5058066097 @default.
• W2081982108 date "1980-04-01" @default.
• W2081982108 modified "2023-09-27" @default.
• W2081982108 title "Polarographic detection for high-performance liquid chromatography using a flow-through detector" @default.
• W2081982108 cites W1963834980 @default.
• W2081982108 cites W1967178375 @default.
• W2081982108 cites W1982561783 @default.
• W2081982108 cites W1982920269 @default.
• W2081982108 cites W1991095254 @default.
• W2081982108 cites W1994942622 @default.
• W2081982108 cites W1998366991 @default.
• W2081982108 cites W2002073490 @default.
• W2081982108 cites W2005131051 @default.
• W2081982108 cites W2010396165 @default.
• W2081982108 cites W2016462789 @default.
• W2081982108 cites W2019217035 @default.
• W2081982108 cites W2026528267 @default.
• W2081982108 cites W2029613733 @default.
• W2081982108 cites W2038891138 @default.
• W2081982108 cites W2049445380 @default.
• W2081982108 cites W2055785047 @default.
• W2081982108 cites W2056500298 @default.
• W2081982108 cites W2061739231 @default.
• W2081982108 cites W2078645975 @default.
• W2081982108 cites W2085996234 @default.
• W2081982108 cites W2090170593 @default.
• W2081982108 cites W2102477919 @default.
• W2081982108 cites W2144404595 @default.
• W2081982108 cites W2315944928 @default.
• W2081982108 cites W2320159335 @default.
• W2081982108 cites W2320178910 @default.
• W2081982108 cites W2328752537 @default.
• W2081982108 cites W4229834787 @default.
• W2081982108 cites W4243291387 @default.
• W2081982108 cites W4252429348 @default.
• W2081982108 doi "https://doi.org/10.1016/s0021-9673(00)86363-3" @default.
• W2081982108 hasPublicationYear "1980" @default.
• W2081982108 type Work @default.
• W2081982108 sameAs 2081982108 @default.
• W2081982108 citedByCount "25" @default.
• W2081982108 crossrefType "journal-article" @default.
• W2081982108 hasAuthorship W2081982108A5035615805 @default.
• W2081982108 hasAuthorship W2081982108A5041428842 @default.
• W2081982108 hasAuthorship W2081982108A5058066097 @default.
• W2081982108 hasConcept C110084920 @default.
• W2081982108 hasConcept C113196181 @default.
• W2081982108 hasConcept C119128265 @default.
• W2081982108 hasConcept C120665830 @default.
• W2081982108 hasConcept C121332964 @default.
• W2081982108 hasConcept C12707504 @default.
• W2081982108 hasConcept C147789679 @default.
• W2081982108 hasConcept C172120300 @default.
• W2081982108 hasConcept C17525397 @default.
• W2081982108 hasConcept C178790620 @default.
• W2081982108 hasConcept C179104552 @default.
• W2081982108 hasConcept C179998833 @default.
• W2081982108 hasConcept C185592680 @default.
• W2081982108 hasConcept C188518856 @default.
• W2081982108 hasConcept C20556612 @default.
• W2081982108 hasConcept C2776278163 @default.
• W2081982108 hasConcept C2779603750 @default.
• W2081982108 hasConcept C43617362 @default.
• W2081982108 hasConcept C44280652 @default.
• W2081982108 hasConcept C52859227 @default.
• W2081982108 hasConcept C57879066 @default.
• W2081982108 hasConcept C62520636 @default.
• W2081982108 hasConcept C72343979 @default.
• W2081982108 hasConcept C73826308 @default.
• W2081982108 hasConcept C94915269 @default.
• W2081982108 hasConceptScore W2081982108C110084920 @default.
• W2081982108 hasConceptScore W2081982108C113196181 @default.
• W2081982108 hasConceptScore W2081982108C119128265 @default.
• W2081982108 hasConceptScore W2081982108C120665830 @default.
• W2081982108 hasConceptScore W2081982108C121332964 @default.
• W2081982108 hasConceptScore W2081982108C12707504 @default.
• W2081982108 hasConceptScore W2081982108C147789679 @default.
• W2081982108 hasConceptScore W2081982108C172120300 @default.
• W2081982108 hasConceptScore W2081982108C17525397 @default.
• W2081982108 hasConceptScore W2081982108C178790620 @default.
• W2081982108 hasConceptScore W2081982108C179104552 @default.
• W2081982108 hasConceptScore W2081982108C179998833 @default.
• W2081982108 hasConceptScore W2081982108C185592680 @default.
• W2081982108 hasConceptScore W2081982108C188518856 @default.
• W2081982108 hasConceptScore W2081982108C20556612 @default.
• W2081982108 hasConceptScore W2081982108C2776278163 @default.
• W2081982108 hasConceptScore W2081982108C2779603750 @default.
• W2081982108 hasConceptScore W2081982108C43617362 @default.
• W2081982108 hasConceptScore W2081982108C44280652 @default.
• W2081982108 hasConceptScore W2081982108C52859227 @default.
• W2081982108 hasConceptScore W2081982108C57879066 @default.
• W2081982108 hasConceptScore W2081982108C62520636 @default.
• W2081982108 hasConceptScore W2081982108C72343979 @default.
• W2081982108 hasConceptScore W2081982108C73826308 @default.
• W2081982108 hasConceptScore W2081982108C94915269 @default.

• next