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- W2082002227 abstract "Crystalline 2,4-dihydroxybenzylidene-4-aminoantipyrine (HL·0.5H 2 O, Ia ) undergoes desolvation followed by phase transformation in the solid state upon heating. The UO 2 (VI) complex of this ligand [UO 2 L(OOCCH 3 )·2H 2 O, IIa ] shows thermochromism in the solid state. This thermochromism has been attributed to desolvation accompanied by a phase change. These were studied using differential thermal analysis, thermogravimetric analysis, IR spectroscopy, X-ray powder diffraction and electrical conductivity. The energy of activation E a of the desolvation processes and the reaction orders were evaluated." @default.
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- W2082002227 date "1990-08-01" @default.
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- W2082002227 title "Phase change and thermochromism of crystalline 2,4-dihydroxybenzylidene-4-aminoantipyrine and its UO2(VI) complex in the solid state" @default.
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- W2082002227 doi "https://doi.org/10.1016/0040-6031(90)80218-n" @default.
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