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- W2082009003 abstract "Abstract The preparation and characterisation of the title complex, CoL3, is reported. The crystal structure determination shows that the complex has three-fold symmetry and that the three ligands each coordinate via the ketonic oxygen (Co-O 1.931(4) Å) and oximic nitrogen atoms (Co-N 1.892(4) Å) such that the overall configuration about the cobalt atom is fac. Crystals of CoL3 are trigonal, space group R3c, a = 18.645(5), c = 14.08(1) Å, V = 4237(2) Å3 and Z = 6. The structure was refined by a full-matrix least-squares procedure to Rw = 0.031 for 741 observed reflections. Key Words: cobalt(III)stereochemistrycrystal structureferroverdin" @default.
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- W2082009003 date "1995-10-01" @default.
- W2082009003 modified "2023-10-16" @default.
- W2082009003 title "SYNTHESIS AND X-RAY STRUCTURE OF TRIS[1-PHENYL-2-(HYDROXIMINO)-1,3-BUTANEDIONATO]COBALT(III) – A STRUCTURAL ANALOGUE OF NATURALLY OCCURRING FERROVERDIN" @default.
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- W2082009003 doi "https://doi.org/10.1080/00958979508022564" @default.
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