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- W2082014178 abstract "Phosphorus hydrazides PhP(O)[N(Me)NH2]2, (S)P[N(Me)NH2]3, and N3P3[N(Me)NH2]6 were condensed with 7-diethylaminocoumarin-3-aldehyde (RCHO) to afford the corresponding hydrazones PhP(O)[N(Me)NCHR]2 (1), (S)P[N(Me)NCHR]3 (2), and N3P3[N(Me)NCHR]6 (3). The structural characterization of 1–3 was carried out by their HRMS, 1H and 31P{1H} NMR spectra. The molecular structure of 2 was established by a single-crystal X-ray analysis. Interaction of 1 and 2 with various transition metal ions revealed substantial fluorescence enhancement upon interaction with Cu2+ enabling a selective detection mechanism for this metal ion. However, such a fluorescence enhancement was not observed in the case of 3. A 1:1 complex [2·Zn][ClO4]2·4CH2Cl2 was isolated in the reaction of 2 with Zn(ClO4)2·6H2O. The molecular structure of this complex revealed that the ZnII is encapsulated by the ligand utilizing a 3N, 3O coordination set." @default.
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- W2082014178 date "2009-11-01" @default.
- W2082014178 modified "2023-10-16" @default.
- W2082014178 title "Phosphorus-supported multidentate coumarin-containing fluorescence sensors for Cu2+" @default.
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- W2082014178 doi "https://doi.org/10.1016/j.tet.2009.09.040" @default.
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