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- W2082014441 abstract "Abstract By the electrocrystallization technique, it has been possible to synthesize a new charge transfer salt, associating the organic anion ABTS2–, the radical anion ABTS– (ABTS is the commercial name of the diammonium salt of the 2-2’ azinobis–3 ethyl benzothiazoline sulfonate), and the inorganic cation La3+. From single crystal X-ray diffraction data, the crystal structure was solved at 200 K. La3(ABTS)5(H2O)31 belongs to the triclinic symmetry space group P 1 ¯ with the cell parameters: a = 18.342(4) A, b = 17.720 (4) A, c = 20.394(4) A, α = 87.97(3)°, β = 79.08(3)°, γ = 85.21(3)°, V = 6 850(2) A3 and Z = 2. The crystalline network reveals a two-dimensional character based on an alternation of organic and inorganic layers. A valence bond calculation corresponds to a lanthanum in a (+III) oxidation state. This compound is a mixed anionic valence salt, and in accordance with the charge equilibrium, its formulation must be written (La3+)3(ABTS2–)4(ABTS•–)1(H2O)31." @default.
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- W2082014441 date "2001-12-01" @default.
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- W2082014441 title "Synthèse et résolution structurale d’un nouveau sel à transfert de charge associant l’anion organique ABTS2– et son radical ABTS•– avec le cation inorganique La3+ : La3(ABTS)5(H2O)31" @default.
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- W2082014441 doi "https://doi.org/10.1016/s1387-1609(01)01352-4" @default.
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