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- W2082038460 abstract "Abstract A number of acidopentammineruthenium(III) compounds having C4v micro-symmetry about RuIII were prepared and characterized. Solution optical spectra below 50 kK were recorded, and charged-transfer, dd, and internal transitions were observed. Tetragonal spin-orbit components of the charge-transfer π(NCSe−) →(Ru(xz,yz) transitions are only weakly antibonding, on the basis of band widths, relative to the ground state Γ7t(2Et0. dd transitions are assigned to 2T1g, 2T2gb, and Eg. The latter are not split sufficiently to permit observation of ther C4v components. The observed spectrochemical series of L in [Ru(NH3)5L]Q is NH3>NCO−>OAc−>SCN−>SeCn− on the basis of the energy of the first dd band." @default.
- W2082038460 created "2016-06-24" @default.
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- W2082038460 date "1971-03-01" @default.
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- W2082038460 title "Chemistry and optical properties of 4d and 5d transition metal compounds. II. synthesis and optical spectra of acetatopentammineruthenium(III) and pseudohalogenpentammineruthenium(III) compounds" @default.
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- W2082038460 doi "https://doi.org/10.1016/s0020-1693(00)95931-0" @default.
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