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• W2082043903 abstract "Summary Results are reported for the irreversible electrochemical reduction of Cr(III) to Cr(II) at a DME in aqueous acid perchlorate medium, investigated by d.c., a.c. and Kalousek polarography. The rate constant of the forward reaction has been found to increase in the order: [Cr(H 2 O) 6 ] 3+ ∼[Cr(H 2 O) 5 NCS] 2+ ∼[Cr(H 2 O) 5 -N 3 ] 2+ ∼ trans - [Cr(H 2 O) 4 (N 3 ) 2 ] + trans -[Cr(H 2 O) 4 (NCS) 2 ] + cis -[Cr(H 2 O) 4 -(NCS) 2 ] + . No clear correlation was observed between the rate constant of the forward reaction and the electronic spectrum of a given species, and it was concluded that the electrochemical reduction of Cr(III) is not necessarily governed by the same factors as the homogeneous reduction by Cr(II). For the reduction of the isothiocyanato complexes, a mechanism is suggested involving a bridged transition state in which the sulphur end points towards the mercury surface." @default.
• W2082043903 created "2016-06-24" @default.
• W2082043903 creator A5090405753 @default.
• W2082043903 date "1970-05-01" @default.
• W2082043903 modified "2023-09-26" @default.
• W2082043903 title "Polarographic reduction of hexaquo-isothiocyanato-and azido-chromium(III) ions on a dropping mercury electrode in aqueous acid perchlorate solution" @default.
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• W2082043903 doi "https://doi.org/10.1016/s0022-0728(70)80100-0" @default.
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