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• W2082091215 abstract "By using metal ions as templates for polymer synthesis, functional materials with a wide range of molecular architectures may be readily generated. Polystyrene macroligands, bpyPS and bpyPS2, with bipyridine (bpy) donors at the end and center of the chain, respectively, were generated by copper-catalyzed atom transfer radical polymerization (ATRP). Heteroleptic polymeric Ru(II) tris(α-diimine) complexes were prepared by combining nonpolymeric ligands and polymeric bpyPSn ligands of different molecular weights. The reaction of bpyPS2 with Ru(DMSO)4Cl2 in CHCl3 solution to form a putative [Ru(bpyPS2)(DMSO)mCl2]2+ intermediate, followed by dehalogenation with AgPF6 in the presence of excess 2,2‘-bipyridine, led to linear polymeric complexes, [Ru(bpyPS2)(bpy)2]2+. More versatile were sequences involving chelation of 2 equiv of a bpyPSn, followed by association of another polymeric or nonpolymeric ligand with the Ru(II) center. Ruthenium-centered linear polymers, [Ru(bpyPS)2(L)]2+ (L = bpy or 4,4‘-bis(hydroxymethyl)-2,2‘-bipyridine), and analogous four-arm stars, [Ru(bpyPS2)2(L)]2+ (L = bpy, 1,10-phenathroline, 4,4‘-bis(hydroxymethyl)-2,2‘-bipyridine, and 4,4‘-bis(tricosanyl)-2,2‘-bipyridine) were prepared in this fashion. Reactions forming [Ru(bpyPSn)2Cl2] and [Ru(bpyPSn)2(solvent)m]2+ intermediates showed a marked molecular weight dependence. In certain cases, reactivity at the Ru center could be modulated by changing the polarity of the reaction media (DME vs DME/MeOH). Differences in the conformation of polystyrene chains in different solvents were exploited as a “protecting group” strategy in polymeric metal complex synthesis. By using two different kinds of bpyPSn macroligands, homo-block copolymer Ru-centered stars, [Ru(bpyPS)2(bpyPS2)]2+ and [Ru(bpyPS2)2(bpyPS)]2+, were generated. GPC and UV/vis spectroscopy confirm that the Ru(II) chromophores are associated with eluting polymer fractions and allow for comparison of relative chelation efficiencies." @default.
• W2082091215 created "2016-06-24" @default.
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• W2082091215 date "2000-09-19" @default.
• W2082091215 modified "2023-10-15" @default.
• W2082091215 title "The Importance of Macroligand Molecular Weight and Solvent Polarity in Modulating Metal Core Reactivity in Heteroleptic Polymeric Ruthenium Tris(bipyridine) Complex Synthesis" @default.
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• W2082091215 cites W1966545431 @default.
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• W2082091215 cites W1981733988 @default.
• W2082091215 cites W1983101851 @default.
• W2082091215 cites W1983335169 @default.
• W2082091215 cites W1984224301 @default.
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• W2082091215 cites W1999284708 @default.
• W2082091215 cites W2000946817 @default.
• W2082091215 cites W2003085433 @default.
• W2082091215 cites W2004190156 @default.
• W2082091215 cites W2007891647 @default.
• W2082091215 cites W2009765332 @default.
• W2082091215 cites W2013749421 @default.
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• W2082091215 doi "https://doi.org/10.1021/ma000837e" @default.
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