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- W2082091837 abstract "Abstract The diffusion of 109Cd and 60Co in monocrystalline silver was investigated over a temperature range from about 375 to 650°C using a chemical film sectioning technique. Penetration depths studied were limited to a region that has previously exhibited unusually steep penetration profiles for high temperature diffusion of 60Co in Ag. This anomalous behavior or “near-surface effect” is characterized by abnormally low diffusivities for penetration depths up to several microns from the surface. For both of the isotope tracers, a near-surface effect was observed at the higher temperatures of the range. However, the diffusivities measured at the lower temperatures were in agreement with extrapolations of hightemperature lattice diffusion data in the literature. An apparent transition in diffusion mechanism was noted from plots of the logarithm of the diffusivity vs. the reciprocal of the absolute temperature. The transitional behavior is described in terms of oxidation kinetics. A possible mechanism for the near surface effect, that has an activation energy and pre-exponential factor corresponding to that observed in the transition is discussed in detail." @default.
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- W2082091837 date "1972-09-01" @default.
- W2082091837 modified "2023-09-27" @default.
- W2082091837 title "Low temperature diffusion of cobalt and cadmium in silver" @default.
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- W2082091837 doi "https://doi.org/10.1016/0001-6160(72)90171-x" @default.
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