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• W2082154710 startingPage "2397" @default.
• W2082154710 abstract "We here suggest and evaluate a methodology for the measurement of specific interatomic distances from a combination of theoretical calculations and experimentally measured (13)C kinetic isotope effects. This process takes advantage of a broad diversity of transition structures available for the epoxidation of 2-methyl-2-butene with oxaziridines. From the isotope effects calculated for these transition structures, a theory-independent relationship between the C-O bond distances of the newly forming bonds and the isotope effects is established. Within the precision of the measurement, this relationship in combination with the experimental isotope effects provides a highly accurate picture of the C-O bonds forming at the transition state. The diversity of transition structures also allows an evaluation of the Schramm process for defining transition-state geometries on the basis of calculations at nonstationary points, and the methodology is found to be reasonably accurate." @default.
• W2082154710 created "2016-06-24" @default.
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• W2082154710 date "2009-01-15" @default.
• W2082154710 modified "2023-09-25" @default.
• W2082154710 title "Transition-State Geometry Measurements from ¹³C Isotope Effects. The Experimental Transition State for the Epoxidation of Alkenes with Oxaziridines" @default.
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• W2082154710 doi "https://doi.org/10.1021/ja8088636" @default.
• W2082154710 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/2640442" @default.
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• W2082154710 hasPublicationYear "2009" @default.
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