FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2082170914> ?p ?o ?g. }

• W2082170914 endingPage "1470" @default.
• W2082170914 startingPage "1462" @default.
• W2082170914 abstract "Electron spin resonance imaging (ESRI) was applied to the study of thermal degradation at 393 K of poly(acrylonitrile-butadiene-styrene) (ABS) prepared by emulsion polymerization and containing 25% wt butadiene (ABS-25B). The polymer was doped with 1 or 2% wt Tinuvin 770 as the hindered amine stabilizer (HAS). The spatial distribution of the HAS-derived nitroxide radicals, obtained by 1D ESRI, was initially homogeneous, but became heterogeneous through sample depth with increasing treatment time, t. The spatial variation of ESR line shaping with sample depth was visualized by 2D spectral-spatial ESRI. ESR spectra along the sample depth, obtained by nondestructive (“virtual”) slicing of the 2D images, were used to deduce the relative intensity of nitroxide radicals present in two dynamically distinct sites; the sites were assigned to butadiene-rich (fast component) and SAN-rich domains (slow component), respectively. 1D and 2D ESRI allowed the determination of the extent of degradation within morphologically-distinct domains as a function of sample depth and treatment time. The results from the ESRI experiments were substantiated by attenuated total reflectance (ATR)-FTIR spectroscopy of the outer layer (500 μm thick) of the polymer. Both techniques indicated faster degradation of polymer samples that contained the higher HAS content, 2% wt. Comparison with the results obtained for a parallel study of ABS prepared by mass polymerization and containing 10% wt butadiene (ABS-10B) indicated clearly that the rate of degradation of the polymer prepared by emulsion polymerization (ABS-25B) is significantly reduced. This result can be explained by the formation of cross-linked “composite” networks during emulsion polymerization, which leads to greater thermal stability." @default.
• W2082170914 created "2016-06-24" @default.
• W2082170914 creator A5063287358 @default.
• W2082170914 creator A5085004006 @default.
• W2082170914 date "2006-07-01" @default.
• W2082170914 modified "2023-10-15" @default.
• W2082170914 title "ESR imaging and FTIR study of thermally treated poly(acrylonitrile-butadiene-styrene) (ABS) containing a hindered amine stabilizer: Effect of polymer morphology, and butadiene and stabilizer content" @default.
• W2082170914 cites W1488679575 @default.
• W2082170914 cites W1974104917 @default.
• W2082170914 cites W1995389944 @default.
• W2082170914 cites W1999763149 @default.
• W2082170914 cites W2002598747 @default.
• W2082170914 cites W2003108152 @default.
• W2082170914 cites W2011759517 @default.
• W2082170914 cites W2015117492 @default.
• W2082170914 cites W2016134661 @default.
• W2082170914 cites W2020471701 @default.
• W2082170914 cites W2021305375 @default.
• W2082170914 cites W2024683272 @default.
• W2082170914 cites W2028198717 @default.
• W2082170914 cites W2033794074 @default.
• W2082170914 cites W2046147191 @default.
• W2082170914 cites W2047122296 @default.
• W2082170914 cites W2051441638 @default.
• W2082170914 cites W2060614773 @default.
• W2082170914 cites W2068897546 @default.
• W2082170914 cites W2072038016 @default.
• W2082170914 cites W2078285048 @default.
• W2082170914 cites W2080228784 @default.
• W2082170914 cites W2117993658 @default.
• W2082170914 cites W92138806 @default.
• W2082170914 doi "https://doi.org/10.1016/j.polymdegradstab.2005.10.011" @default.
• W2082170914 hasPublicationYear "2006" @default.
• W2082170914 type Work @default.
• W2082170914 sameAs 2082170914 @default.
• W2082170914 citedByCount "17" @default.
• W2082170914 countsByYear W20821709142012 @default.
• W2082170914 countsByYear W20821709142013 @default.
• W2082170914 countsByYear W20821709142014 @default.
• W2082170914 countsByYear W20821709142015 @default.
• W2082170914 countsByYear W20821709142017 @default.
• W2082170914 countsByYear W20821709142018 @default.
• W2082170914 countsByYear W20821709142019 @default.
• W2082170914 countsByYear W20821709142020 @default.
• W2082170914 countsByYear W20821709142021 @default.
• W2082170914 crossrefType "journal-article" @default.
• W2082170914 hasAuthorship W2082170914A5063287358 @default.
• W2082170914 hasAuthorship W2082170914A5085004006 @default.
• W2082170914 hasConcept C111998727 @default.
• W2082170914 hasConcept C127413603 @default.
• W2082170914 hasConcept C159985019 @default.
• W2082170914 hasConcept C160892712 @default.
• W2082170914 hasConcept C169912494 @default.
• W2082170914 hasConcept C185592680 @default.
• W2082170914 hasConcept C188027245 @default.
• W2082170914 hasConcept C192562407 @default.
• W2082170914 hasConcept C199002037 @default.
• W2082170914 hasConcept C2781431410 @default.
• W2082170914 hasConcept C42360764 @default.
• W2082170914 hasConcept C44228677 @default.
• W2082170914 hasConcept C521977710 @default.
• W2082170914 hasConceptScore W2082170914C111998727 @default.
• W2082170914 hasConceptScore W2082170914C127413603 @default.
• W2082170914 hasConceptScore W2082170914C159985019 @default.
• W2082170914 hasConceptScore W2082170914C160892712 @default.
• W2082170914 hasConceptScore W2082170914C169912494 @default.
• W2082170914 hasConceptScore W2082170914C185592680 @default.
• W2082170914 hasConceptScore W2082170914C188027245 @default.
• W2082170914 hasConceptScore W2082170914C192562407 @default.
• W2082170914 hasConceptScore W2082170914C199002037 @default.
• W2082170914 hasConceptScore W2082170914C2781431410 @default.
• W2082170914 hasConceptScore W2082170914C42360764 @default.
• W2082170914 hasConceptScore W2082170914C44228677 @default.
• W2082170914 hasConceptScore W2082170914C521977710 @default.
• W2082170914 hasIssue "7" @default.
• W2082170914 hasLocation W20821709141 @default.
• W2082170914 hasOpenAccess W2082170914 @default.
• W2082170914 hasPrimaryLocation W20821709141 @default.
• W2082170914 hasRelatedWork W1567719389 @default.
• W2082170914 hasRelatedWork W1978719757 @default.
• W2082170914 hasRelatedWork W1979313898 @default.
• W2082170914 hasRelatedWork W2074891600 @default.
• W2082170914 hasRelatedWork W2104076717 @default.
• W2082170914 hasRelatedWork W2344434547 @default.
• W2082170914 hasRelatedWork W2388673930 @default.
• W2082170914 hasRelatedWork W2600143267 @default.
• W2082170914 hasRelatedWork W2952855615 @default.
• W2082170914 hasRelatedWork W3167885466 @default.
• W2082170914 hasVolume "91" @default.
• W2082170914 isParatext "false" @default.
• W2082170914 isRetracted "false" @default.
• W2082170914 magId "2082170914" @default.
• W2082170914 workType "article" @default.