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- W2082172838 abstract "The mean-square length 〈R2〉 of a polymer molecule composed of n segments is assumed to behave asymptotically as 〈Rn2〉 ∼ An1+ε for large n, where A is a constant and ε takes into account the excluded-volume effect. This paper compares calculations of 〈Rn2〉 for the model of a polymethylene chain without excluded volume studied by Flory and Jerigan with the model of a polymer as a self-avoiding walk on a crystal lattice which has been studied by the method of exact enumeration developed by Domb. For the first model ε = 0, whereas for the second, which includes the excluded-volume effect, ε = 15. It is shown using the extrapolation technique of Neville tables that the exact-enumeration method correctly predicts ε = 0 for the Flory–Jernigan model. However, the rate of convergence is very much slower than comparable calculations using the fcc lattice and taking account of excluded volume." @default.
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- W2082172838 date "1970-01-15" @default.
- W2082172838 modified "2023-09-24" @default.
- W2082172838 title "Estimation of High‐Polymer Excluded Volume from Numerical Studies on Short Chains" @default.
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- W2082172838 doi "https://doi.org/10.1063/1.1673033" @default.
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