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- W2082185838 abstract "N,N)′-Ditosylschwefeldiimid (1) ist ein auserordentlich reaktives Enophil, dessen Umsetzung mit einer grosen Anzahl von Propenderivaten 2 in guter Ausbeute die Sulfinamidine 3 oder durch deren sigmatrope Umlagerung die Diaminosulfanderivate 4 liefert. Die 1H-NMR-spektrometrischen Untersuchungen dieser Umsetzungen erlauben Aussagen uber die relativen Reaktivitaten der En-Komponenten und die Regio- und Stereoselektivitat der Reaktionsfolge.The Chemistry of Sulfur Diimides, 81). — Ene Reactions with Sulfur Diimides — Structure of the Ene Components and Reactivity in the Reaction with Ditosyl Sulfur DiimideN,N)′-Ditosyl sulfur diimide (1) is an exceptionally reactive enophilic compound. Its reactions with many allylic derivatives give sulfinamidines 3 or — by sigmatropic rearrangements of 3 — diamino sulfane derivatives 4, respectively, in good yields. Conclusions concerning relative reactivities of the ene compounds and the regio- and stereoselectivity of the reaction sequence are drawn from the results of the NMR spectrometric investigation of the reactions." @default.
- W2082185838 created "2016-06-24" @default.
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- W2082185838 date "1980-04-30" @default.
- W2082185838 modified "2023-09-26" @default.
- W2082185838 title "Zur Chemie der Schwefeldiimide, 8. En-Reaktionen mit Schwefeldiimiden — Struktur der En-Komponente und Reaktivität bei der Umsetzung mit Ditosylschwefeldiimid" @default.
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- W2082185838 doi "https://doi.org/10.1002/jlac.198019800415" @default.
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