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- W2082281307 abstract "Attempts are presented for the preparation of complexes of starch with a series of dioic acids (oxalic, malonic, succinic, glutaric and adipic). The complexes are isolated and characterized by potentiometric titration, powder X-ray diffraction, characteristics of gelation and differential scanning calorimetry. These complexes contain dioic acids on the level of 1−3g per 1g of starch. Oxalic acid forms a surface complex with crosslinking involving both its carboxylic groups. Malonic acid forms surface complex with involvement of only one of its carboxylic groups and all three succinic, glutaric and adipic acids form inclusion complexes. Komplexe von Stärke mit Dicarboxylsäuren. Es werden Versuche aufgezeigt zur Darstellung von Stärkekomplexen mit einer Reihe von Dicarboxylsäuren (Oxal-, Malon-, Bernstein-, Glutar- und Adipinsäure). Die Komplexe wurden isoliert und durch potentiometrische Titration, Pulver-Röntgenbeugung. Verkleisterungscharakteristika und Differential-Rasterkalorimetrie charakterisiert. Diese Komplexe enthalten Dicarboxylsäuren bis zu 10−3 g pro lg Starke. Oxalsaure bildet einen Oberflächenkomplex mit Vernetzung ihrer beiden Carboxylgruppen. Malosäure bildet einen Oberflächenkomplex unter Einbeziehung von nur einer ihrer Carboxylgruppen, und Bernsteinsäure, Glutarsäure und Adipinsäure bilden Einschlußkomplexe." @default.
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- W2082281307 date "1995-01-01" @default.
- W2082281307 modified "2023-10-13" @default.
- W2082281307 title "Complexes of Starch with Dioic Acids" @default.
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- W2082281307 doi "https://doi.org/10.1002/star.19950470304" @default.
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