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- W2082300375 abstract "Abstract The crystal and molecular structures of a new crystalline modification of the mesogenic PCH8 and of two solid modifications of PCH9 are described: PCH8B: Triclinic, space group P1, a = 6.369 (2), b = 11.907 (3). c = 13.119 (3) Å, α = 77.39 (1), β = 78.48 (1), γ = 77.68 (a)[ddot]; Z = 2; PCH9A: Monoclinic, space group P21/c, a = 21.562 (4), b = 5.158 (1), c = 19.326 (4) Å, β = 112.99 (1)[ddot], Z = 4; PCH9B: Triclinic, space group P1, a = 7.622 (2), b = 11.372 (3), c = 23.574 (6) Å, α = 94.20 (1), β = 95.68 (1), γ = 97.01 (l)[ddot], Z = 4. PCH9A is isostructural with PCH8A (Paulus and Haase),2 showing overlapping of the cyanophenyl groups in a head to tail manner. PCH8B and PCH9B are different from the A-modification and different from each other. PCH83 shows antiparallel CN‒CN correlation interpreted as dimers of infinite stacking, for PCH9B four molecules are showing antiparallel CN-CN clustering in form of an island. In all of the described modifications the alkylcyclohexyl groups are unflexible whereas the angle between the phenyl and the cyclohexyl groups is more flexible." @default.
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- W2082300375 date "1991-03-01" @default.
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- W2082300375 title "The Crystal and Molecular Structures of a Second Crystalline Modification of the Mesogenic trans-4-<i>n</i>-octyl-(4′-cyanophenyl)- cyclohexane (PCH8B) and of Two Crystalline Modifications of the Mesogenic trans-4-<i>n</i>-nonyl-(4′-cyanophenyl)- cyclohexanes (PCH9A, PCH9B)" @default.
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- W2082300375 doi "https://doi.org/10.1080/00268949108029702" @default.
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