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• W2082315926 startingPage "837" @default.
• W2082315926 abstract "A previously unreported series of N-(substituted benzalamino)phthalimides was investigated by using the combined techniques of high resolution electron ionization mass spectrometry, metastable decomposition, and collisional activation mass spectrometry. The predominate fragmentation pathway is a McLafferty-type rearrangement. There also occurs, to a lesser extent, a transfer of hydrogen that originates from a substituent remote from the phthalimide moiety and terminates on the phthalimide, The process is interpreted as proceeding via an ion-neutral complex. The effects of substituents on both of the aforementioned fragmentation pathways provide a striking example that gives quantitative evidence for Stevenson's rule. The substituent effects are responsible for a trend in ion abundance that shows a sharp reversal at approximately the ionization energy of the iminium isomer of the phthalimide molecular ion." @default.
• W2082315926 created "2016-06-24" @default.
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• W2082315926 date "1994-09-01" @default.
• W2082315926 modified "2023-09-24" @default.
• W2082315926 title "The decompositions of <i>N</i>-(substituted benzalamino)phthalimide radical cations embody ion-neutral complexes and Stevenson’s rule" @default.
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• W2082315926 doi "https://doi.org/10.1016/1044-0305(94)87006-3" @default.
• W2082315926 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/24222031" @default.
• W2082315926 hasPublicationYear "1994" @default.
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