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- W2082342766 abstract "Acid catalyzed reaction of cyelododecane-1,2-dione VI with dimethyl,3-ketoglutarate II led to the formation of methyl (E)-6,7,8,9,10,11,12,13-octahydro-3-(methoxycarbonyl)cyclododeca-[b]furan-2-aeetate IX, presumably formed through the dihydrodihydroxy furan VIII. This dihydrofuran intermediate VIII was shown to be characteristic of the reaction of 2-substituted carbonyl-compounds with 11 for both α-chlorocyclohexanone and α-chlorocyclopentanone furnished furans XVIa and XX, respectively, when treated with 11. The effect of dihydrodihydroxy-furan intermediates on the course of such reactions is discussed." @default.
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- W2082342766 date "1977-08-04" @default.
- W2082342766 modified "2023-10-16" @default.
- W2082342766 title "Reaction of carbonyl compounds with dimethyl 3-ketoglutarate. Synthesis of bicyclic furan derivatives" @default.
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- W2082342766 doi "https://doi.org/10.1002/jhet.5570140501" @default.
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