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- W2082349067 abstract "Theoretically predicted effect of odd-even pattern of electron pairing on behavior of gold clusters in polyaniline/AuN (N = 0 to 8) has been confirmed experimentally. In these composites the atomic Au clusters with even number of atoms exhibit higher catalytic activity for electrochemical oxidation of n-propanol in 1 M NaOH than the odd-number atoms clusters. Also, infrared spectroscopy shows that even numbered PANI/AuN composites affect the N-H stretching vibration more strongly than the corresponding odd numbered ones. This behavior matches the theoretically predicted variations of HOMO-LUMO gap energy and the stability of the atomic Au clusters. It also agrees with the earlier experimental work in which the UPS spectra of isolated, mass-selected Au clusters have been reported." @default.
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- W2082349067 date "2012-01-01" @default.
- W2082349067 modified "2023-10-18" @default.
- W2082349067 title "Odd-Even Pattern Observed in Polyaniline/(Au<sub>0</sub>– Au<sub>8</sub>) Composites" @default.
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- W2082349067 doi "https://doi.org/10.1149/2.053203jes" @default.
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