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• W2082511273 abstract "A potassium ion-selective electrode based on a cobalt(II)-hexacyanoferrate(III) (CHCF) film-modified glassy carbon electrode is proposed. The electroactive film is introduced onto the glassy carbon electrode surface by electrodeposition of cobalt, which forms a thin CHCF film on subsequent anodic scanning in KClHCl solution (pH 5.0–5.5) containing K3Fe(CN)6. The thickness of the film on the electrode surface can be controlled by changing the electrodeposition time and the concentrations of cobalt(II) and Fe(CN)3−6 ions. The modified electrode exhibits a linear response in the concentration range 1 × 10−1 −3 × 10−5 M potassium ion activity, with a near-Nernstian slope (48–54 mV per decade) at 25 ± 1°C. The detection limit is 1 × 10−5 M. The stability, response time and selectivity were investigated. The electrode exhibits good selectivity for potassium ion with the twelve cations investigated. The relative standard deviation is 1.5% (n=10). The effects of the thickness of the electroactive film and the pH of the solution on the electrode response were also investigated." @default.
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• W2082511273 date "1991-01-01" @default.
• W2082511273 modified "2023-09-27" @default.
• W2082511273 title "Potassium ion-selective electrode based on a cobalt(II)-hexacyanoferrate film-modified electrode" @default.
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• W2082511273 doi "https://doi.org/10.1016/s0003-2670(00)82476-9" @default.
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