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• W2082542389 abstract "Aqueous poly(phenylacetylene) dispersions were obtained by catalytic polymerization in emulsion with a phosphine-modified Pd(II) catalyst. A range of mono- and bidentate phosphines were screened. A tBu2P(CH2)3PtBu2-modified catalyst exhibits very high rates up to 2 × 105 TO h−1 (TO = moles of monomer converted per mole of metal present in the reaction mixture) in the preparation of colloidally stable poly(phenylacetylene) dispersions. Polymerization in miniemulsion afforded dispersions with up to 36 wt % solids content and average particle sizes of ca. 130 nm. From microemulsions dispersions with ca. 25 nm particle size were obtained." @default.
• W2082542389 created "2016-06-24" @default.
• W2082542389 creator A5003178141 @default.
• W2082542389 creator A5057960044 @default.
• W2082542389 date "2010-10-08" @default.
• W2082542389 modified "2023-09-25" @default.
• W2082542389 title "Aqueous Poly(arylacetylene) Dispersions" @default.
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• W2082542389 doi "https://doi.org/10.1021/ma1013572" @default.
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