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- W2082608684 abstract "A novel open-chain tetradentate ligand having the NSSN donor atom array, S,S′-bis(β-aminoethyl)-trans-1,2-dithiocyclohexane (adch), has been synthesized and the cobalt(III) complexes of [Co(adch)X2]+ (X = Cl−, NO−2, NCS−, X2 =CO2−3) have been prepared. Only the s-cis geometric isomers have been formed. From the reaction between Na3[ CO(CO3)3] and the reacemic adch ligand, the RR-adch ligand is coordinated to the cobalt(III) ion stereospecifically to give the Λ-s-cis-(δλδ)-[Co(adch)Cl2]+ enantiometer complex, while the SS-adch ligand stereospicifically to give the Λ-s-cis-(λδλ)[Co(adch)Cl2]+ enantiometer complex, which have been observed in the crystal structure of the [Co(adch)Cl2]Cl2·C2H5OH complex solved by single-crystal X-ray analysis. The unit cell contains both Λ and Δ complex isomer, two chloride ions and two ethanol molecules. The bond distances in Å: CoS = 2.241 (2) and 2.232 (2), Co N = 1.963 (5) and 1.959 (6) CoCl = 2.262 (2) and 2.250 (2). The coordination geometry about the cobalt atom is a distorted octahedron." @default.
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- W2082608684 title "The sterochemistry and absolute configurations of the metal complexes of novel optically active NSSN system tetradentate ligands. Cobalt(III) complexes of S,S′-bis(β-aminoethyl)-trans-1,2-dithiocyclohexane. Crystal and molecular structure of s-cis[Co(adch)Cl2]Cl·C2H5OH" @default.
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- W2082608684 doi "https://doi.org/10.1016/s0277-5387(97)00141-1" @default.
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