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- W2082634352 abstract "The formation of a potential-dependent surface layer on VO2 electrode has been investigated from the change in conductance of a thin VO2 film electrode by galvanostatic polarization. The VO2 electrode dissolved as vanadate with 100% current efficiency by anodic polarization. At potentials negative to the immersion potential, the VO2 electrode functioned as an insoluble electrode with the formation of the potential-dependent surface layers of the vanadium oxides by lower valence. The change in composition of the surface layers was traced by resistmetry and coulometry, and illustrated against the amount of electric charge passed, taking V7O13, V6O11, V5O9, V4O7, V3O5, and V2O3 as the possible oxides. The composition at vanadium oxides of outer-most layer was plotted against the electrode potential. The plot shows a multi-step figure as in the equilibrium partial pressures of oxygen on vanadium oxides at high temperatures, suggesting a model in which the composition of the outer-most layer of the oxide respo..." @default.
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- W2082634352 date "1979-11-01" @default.
- W2082634352 modified "2023-09-25" @default.
- W2082634352 title "Resistmetric Study of the Potential-sensitive Surface Layer Formed on VO2Electrode in a Neutral Solution" @default.
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- W2082634352 doi "https://doi.org/10.1246/bcsj.52.3253" @default.
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