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• W2082651520 abstract "The structure of LiNbO3-type FeTiO3 and the oxidation state of Fe have been investigated using X-ray diffraction and Mössbauer spectroscopy in the diamond anvil cell up to 18 GPa at room temperature. A structural phase transition is observed at 15.7 GPa from LiNbO3-type to perovskite-type, accompanied by a volume collapse of 1.5%. LiNbO3-type FeTiO3, which is shown to contain only ferrous iron up to this pressure, and no charge transfer is observed. In addition to the c/a axial ratio that has been used to distinguish between ilmenite and LiNbO3-type FeTiO3, the hyperfine parameters (isomer shift and quadrupole splitting) provide an efficient way to discriminate between these two phases." @default.
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• W2082651520 date "2010-09-01" @default.
• W2082651520 modified "2023-09-25" @default.
• W2082651520 title "<i>In situ</i>high-pressure study of LiNbO₃-type FeTiO₃: X-ray diffraction and Mössbauer spectroscopy" @default.
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• W2082651520 doi "https://doi.org/10.1080/08957959.2010.484284" @default.
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