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• W2082652590 abstract "A skeleton key: A biomimetic synthesis of the title natural product was completed in 19 steps and 6.4 % overall yield. Iron(II)-promoted fragmentation of α-alkoxy hydroperoxide and subsequent trapping of the resulting tertiary carbon radical by iodide enabled the highly efficient construction of the challenging 13,14:14,15-disecopregnane skeleton (see scheme; TBDPS=tert-butyldiphenylsilyl). Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article." @default.
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• W2082652590 date "2011-06-17" @default.
• W2082652590 modified "2023-10-18" @default.
• W2082652590 title "Biomimetic Synthesis of 5,6-dihydro-glaucogenin C: Construction of the Disecopregnane Skeleton by Iron(II)-Promoted Fragmentation of an α-Alkoxy Hydroperoxide" @default.
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• W2082652590 doi "https://doi.org/10.1002/anie.201101893" @default.
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