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- W2082665251 abstract "The adsorption of phenol, 4-fluorophenol, and 2,3,4-trifluorophenol on the $mathrm{Si}(111)7ifmmodetimeselsetexttimesfi{}7$ surface is investigated by near edge x-ray absorption fine structure spectroscopy (NEXAFS). A strong polarization dependence of the ${ensuremath{pi}}^{*}$ transitions is observed for fluorinated phenols, while phenol itself is more isotropic. A quantitative method is developed to convert polarization-dependent NEXAFS data into orientational information for such a situation. The model includes two angular degrees of freedom, the tilt angle $ensuremath{gamma}$ of the end group and its rotation angle $ensuremath{beta}$ around the phenyl-to-oxygen bond. The tilt is fixed by the geometry of the free molecule, while the rotation is characterized by an average angle ${ensuremath{beta}}_{0}$ with a Gaussian distribution $ensuremath{sigma}$ due to thermal fluctuations. The model is applicable to a variety of self-assembled monolayers with tailored end groups that are used in molecular electronics and biosensors." @default.
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- W2082665251 date "2006-05-09" @default.
- W2082665251 modified "2023-10-16" @default.
- W2082665251 title "Orientation of fluorophenols on Si(111) by near edge x-ray absorption fine structure spectroscopy" @default.
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- W2082665251 doi "https://doi.org/10.1103/physrevb.73.205315" @default.
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