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- W2082684103 abstract "We discuss how measurements of x-ray circular intensity differentials (XCIDs) could be used to probe the Voigt-Fedorov vector part of optical activity (OA) due to electric dipole-electric quadrupole (E 1E 2) interferences. The first experiment was carried out on a single crystal of zincite (hexagonal ZnO: class 6mm). XCID spectra were recorded in the x-ray resonant diffraction regime near the Zn K edge using the (300) reflection at Bragg angles near 45°. In the x-ray range, the effective operator responsible for the vector part of OA can be assigned to the vector product mathbf {L} times {bOmega }_{L}-{bOmega }_{L} times {mathbf {L}} propto {mathbf {n}} , in which L and ΩL are time-reversal odd operators associated with the orbital angular momentum and the orbital anapole respectively, whereas n is a true time-reversal even electric dipole. This is consistent with the pyroelectric properties of zincite crystals." @default.
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- W2082684103 date "2007-03-16" @default.
- W2082684103 modified "2023-10-18" @default.
- W2082684103 title "Vector part of optical activity probed with x-rays in hexagonal ZnO" @default.
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- W2082684103 doi "https://doi.org/10.1088/0953-8984/19/15/156201" @default.
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