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• W2082724467 abstract "Two aluminum-substituted iron dextran complexes and one nonsubstituted have been synthesized and characterized by Mössbauer spectroscopy over a wide temperature range (10−298 K) and by X-ray powder diffraction at room temperature. The mean coherence lengths in the directions perpendicular to (211) and (200) are different, indicating that the core iron oxide materials are oblong in shape. The X-ray diffraction patterns of all complexes are very similar, with broad, weak peaks at 5.0, 3.3, 2.5, 2.25, 1.6, and 1.8 Å. These values are consistent with cell-contracted akaganeite, β-FeOOH. The three samples exhibit different temperatures for the onset of magnetic splitting in their Mössbauer spectra. The Mössbauer spectra obtained at room temperature can be adequately fitted with a model-independent distribution of quadrupole doublets, while at low temperatures a superposition of distributions of sextets and doublets is required. The obtained Mössbauer parameters are in line with the structural features. This is the first report on nanoscale aluminum-substituted iron oxides as a component of iron dextran." @default.
• W2082724467 created "2016-06-24" @default.
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• W2082724467 date "2000-12-08" @default.
• W2082724467 modified "2023-09-27" @default.
• W2082724467 title "A Study of Aluminum-Substituted Iron Dextran Complexes by Mössbauer Spectroscopy and X-ray Diffraction" @default.
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• W2082724467 doi "https://doi.org/10.1021/cm000489v" @default.
• W2082724467 hasPublicationYear "2000" @default.
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