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• W2082739813 startingPage "14636" @default.
• W2082739813 abstract "The bis(thiolate)Rh(III) complex having a tris(3,5-dimethylpyrazolyl)borate (Tp(Me2)) coligand [Tp(Me2)Rh(SPh)(2)(MeCN)] reacts reversibly with H(2) to form the hydridothiolato complex [Tp(Me2)RhH(SPh)(MeCN)] and PhSH. The benzenedithiolate analogue [Tp(Me2)Rh(o-S(2)C(6)H(4))(MeCN)], which can also heterolytically activate H(2), catalyzes hydrogenation of imines under ambient temperature and pressure with high chemoselectivity." @default.
• W2082739813 created "2016-06-24" @default.
• W2082739813 creator A5017560208 @default.
• W2082739813 creator A5060339714 @default.
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• W2082739813 date "2009-09-29" @default.
• W2082739813 modified "2023-09-30" @default.
• W2082739813 title "Heterolytic Cleavage of Hydrogen Molecule by Rhodium Thiolate Complexes That Catalyze Chemoselective Hydrogenation of Imines under Ambient Conditions" @default.
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• W2082739813 doi "https://doi.org/10.1021/ja905835u" @default.
• W2082739813 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/19824724" @default.
• W2082739813 hasPublicationYear "2009" @default.
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