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• W2082755368 abstract "A catalytic enantioselective syn-1,4-bromolactonization of conjugated (Z)-enynes was reported. Diastereomeric ratios >20:1 and up to 99% enantiomeric excesses were observed. Di-, tri-, and tetra-substituted bromoallenes were prepared together with lactone heterocycles efficiently and stereoselectively. Preliminary investigations suggest that the chiral catalyst may serve as a bifunctional reagent by interacting with both a carboxylic acid nucleophile and NBS electrophile." @default.
• W2082755368 created "2016-06-24" @default.
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• W2082755368 date "2010-03-01" @default.
• W2082755368 modified "2023-10-11" @default.
• W2082755368 title "Enantioselective Bromolactonization of Conjugated (<i>Z</i>)-Enynes" @default.
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• W2082755368 doi "https://doi.org/10.1021/ja100173w" @default.
• W2082755368 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/20192183" @default.
• W2082755368 hasPublicationYear "2010" @default.
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