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• W2082781489 abstract "The deprotonation of imidazolium salts to N-heterocyclic carbenes is often a decisive step in modern catalytic reactions. Therefore, we studied the H/D exchange of the C2 H of 15 imidazolium-substituted calix[4]arenes and 11 nonmacrocyclic model compounds in methanol/water (97:3). The influence of the counterion, substitution directly on the imidazolium unit or on the preorientating calixarene backbone could be studied. The observed exchange rates might give a rational for the suitability of the imidazolium salts as precursors in the Suzuki coupling." @default.
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• W2082781489 date "2006-01-14" @default.
• W2082781489 modified "2023-09-23" @default.
• W2082781489 title "Kinetic Acidity of Supramolecular Imidazolium SaltsEffects of Substituent, Preorientation, and Counterions on H/D Exchange Rates" @default.
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• W2082781489 doi "https://doi.org/10.1021/jo052319d" @default.
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