FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2082795902> ?p ?o ?g. }

• W2082795902 endingPage "1184" @default.
• W2082795902 startingPage "1184" @default.
• W2082795902 abstract "A series of chromium-containing mesoporous MCM-48 molecular sieves, (Cr)MCM-48, with varying Si/Cr (25 − ∝) ratios were synthesized hydrothermally, and characterized systematically by various analytical and spectroscopic techniques. The catalytic performance of the materials was evaluated for the oxidation reactions of certain industrially important organics such as ethylbenzene, cyclohexene and cyclohexane. For all the chosen reactions, the catalyst with a Si/Cr ratio of 50 showed very good conversion and excellent selectivity of the products. Furthermore, (Cr)MCM-48 exhibits much higher activity than the one-dimensional mesoporous (Cr)MCM-41 due to the incorporation of chromium ions in large concentrations as well as to the three-dimensional pore system of the former. Unlike many other chromium-based heterogeneous catalysts, the (Cr)MCM-48 showed only a slight decrease in catalytic activity during first recycling (or second run) experiments, and thereafter it remains nearly the same. Further, the quenching experiments as well as washing studies clearly support the above conclusion. In addition, it can also be deduced from several recycling, washing, filtrate and quenching studies that the leaching of the active chromium ions from the mesoporous matrix is minimal compared to almost all the chromium-based heterogeneous catalysts reported so far. The catalytic activity of (Cr)MCM-48 was also compared with various chromium-containing microporous silicalite-1 and beta, i.e., (Cr)S-1 and (Cr)β, molecular sieves." @default.
• W2082795902 created "2016-06-24" @default.
• W2082795902 creator A5008636167 @default.
• W2082795902 creator A5032220521 @default.
• W2082795902 creator A5069990681 @default.
• W2082795902 date "2003-01-01" @default.
• W2082795902 modified "2023-10-10" @default.
• W2082795902 title "Novel mesoporous (Cr)MCM-48 molecular sieves: Promising heterogeneous catalysts for selective oxidation reactions" @default.
• W2082795902 cites W117720149 @default.
• W2082795902 cites W1589180559 @default.
• W2082795902 cites W1963617634 @default.
• W2082795902 cites W1964107229 @default.
• W2082795902 cites W1971180031 @default.
• W2082795902 cites W1982784029 @default.
• W2082795902 cites W198791733 @default.
• W2082795902 cites W1995970336 @default.
• W2082795902 cites W2004962137 @default.
• W2082795902 cites W2005074617 @default.
• W2082795902 cites W2015871044 @default.
• W2082795902 cites W2023153437 @default.
• W2082795902 cites W2027782347 @default.
• W2082795902 cites W2037037140 @default.
• W2082795902 cites W2050501663 @default.
• W2082795902 cites W2051118901 @default.
• W2082795902 cites W2087105498 @default.
• W2082795902 cites W2091063634 @default.
• W2082795902 cites W2145400939 @default.
• W2082795902 cites W2146375931 @default.
• W2082795902 cites W2163818729 @default.
• W2082795902 cites W2164951096 @default.
• W2082795902 cites W2949571855 @default.
• W2082795902 cites W3968314 @default.
• W2082795902 doi "https://doi.org/10.1039/b301899g" @default.
• W2082795902 hasPublicationYear "2003" @default.
• W2082795902 type Work @default.
• W2082795902 sameAs 2082795902 @default.
• W2082795902 citedByCount "67" @default.
• W2082795902 countsByYear W20827959022012 @default.
• W2082795902 countsByYear W20827959022013 @default.
• W2082795902 countsByYear W20827959022014 @default.
• W2082795902 countsByYear W20827959022015 @default.
• W2082795902 countsByYear W20827959022016 @default.
• W2082795902 countsByYear W20827959022017 @default.
• W2082795902 countsByYear W20827959022018 @default.
• W2082795902 countsByYear W20827959022019 @default.
• W2082795902 countsByYear W20827959022022 @default.
• W2082795902 countsByYear W20827959022023 @default.
• W2082795902 crossrefType "journal-article" @default.
• W2082795902 hasAuthorship W2082795902A5008636167 @default.
• W2082795902 hasAuthorship W2082795902A5032220521 @default.
• W2082795902 hasAuthorship W2082795902A5069990681 @default.
• W2082795902 hasConcept C105281773 @default.
• W2082795902 hasConcept C118792377 @default.
• W2082795902 hasConcept C127413603 @default.
• W2082795902 hasConcept C159390177 @default.
• W2082795902 hasConcept C159750122 @default.
• W2082795902 hasConcept C161790260 @default.
• W2082795902 hasConcept C175583648 @default.
• W2082795902 hasConcept C178790620 @default.
• W2082795902 hasConcept C179104552 @default.
• W2082795902 hasConcept C185592680 @default.
• W2082795902 hasConcept C2778237882 @default.
• W2082795902 hasConcept C2778827576 @default.
• W2082795902 hasConcept C2779484182 @default.
• W2082795902 hasConcept C39432304 @default.
• W2082795902 hasConcept C42360764 @default.
• W2082795902 hasConcept C511782168 @default.
• W2082795902 hasConcept C82776694 @default.
• W2082795902 hasConcept C86381522 @default.
• W2082795902 hasConcept C90982505 @default.
• W2082795902 hasConceptScore W2082795902C105281773 @default.
• W2082795902 hasConceptScore W2082795902C118792377 @default.
• W2082795902 hasConceptScore W2082795902C127413603 @default.
• W2082795902 hasConceptScore W2082795902C159390177 @default.
• W2082795902 hasConceptScore W2082795902C159750122 @default.
• W2082795902 hasConceptScore W2082795902C161790260 @default.
• W2082795902 hasConceptScore W2082795902C175583648 @default.
• W2082795902 hasConceptScore W2082795902C178790620 @default.
• W2082795902 hasConceptScore W2082795902C179104552 @default.
• W2082795902 hasConceptScore W2082795902C185592680 @default.
• W2082795902 hasConceptScore W2082795902C2778237882 @default.
• W2082795902 hasConceptScore W2082795902C2778827576 @default.
• W2082795902 hasConceptScore W2082795902C2779484182 @default.
• W2082795902 hasConceptScore W2082795902C39432304 @default.
• W2082795902 hasConceptScore W2082795902C42360764 @default.
• W2082795902 hasConceptScore W2082795902C511782168 @default.
• W2082795902 hasConceptScore W2082795902C82776694 @default.
• W2082795902 hasConceptScore W2082795902C86381522 @default.
• W2082795902 hasConceptScore W2082795902C90982505 @default.
• W2082795902 hasIssue "8" @default.
• W2082795902 hasLocation W20827959021 @default.
• W2082795902 hasOpenAccess W2082795902 @default.
• W2082795902 hasPrimaryLocation W20827959021 @default.
• W2082795902 hasRelatedWork W1997388563 @default.
• W2082795902 hasRelatedWork W2000307774 @default.
• W2082795902 hasRelatedWork W2028879825 @default.
• W2082795902 hasRelatedWork W2035460258 @default.
• W2082795902 hasRelatedWork W2042306775 @default.

• next