FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2082802658> ?p ?o ?g. }

• W2082802658 endingPage "336" @default.
• W2082802658 startingPage "325" @default.
• W2082802658 abstract "The trichothecene mycotoxin deoxynivalenol (DON) is a well known and common contaminant in food and feed. Acetylated derivatives and other biosynthetic precursors can occur together with the main toxin. A key biosynthetic step towards DON involves an oxidation of the 8-OH group of 7,8-dihydroxycalonectrin. Since analytical standards for the intermediates are not available and these intermediates are therefore rarely studied, we aimed for a synthetic method to invert this reaction, making a series of calonectrin-derived precursors accessible. We did this by developing an efficient protocol for stereoselective Luche reduction at C8. This method was used to access 3,7,8,15-tetrahydroxyscirpene, 3-deacetyl-7,8-dihydroxycalonectrin, 15-deacetyl-7,8-dihydroxycalonectrin and 7,8-dihydroxycalonectrin, which were characterized using several NMR techniques. Beside the development of a method which could basically be used for all type B trichothecenes, we opened a synthetic route towards different acetylated calonectrins." @default.
• W2082802658 created "2016-06-24" @default.
• W2082802658 creator A5004789646 @default.
• W2082802658 creator A5017963229 @default.
• W2082802658 creator A5027745355 @default.
• W2082802658 creator A5067504948 @default.
• W2082802658 creator A5072671157 @default.
• W2082802658 creator A5086789687 @default.
• W2082802658 date "2014-01-10" @default.
• W2082802658 modified "2023-09-27" @default.
• W2082802658 title "Stereoselective Luche Reduction of Deoxynivalenol and Three of Its Acetylated Derivatives at C8" @default.
• W2082802658 cites W1965734985 @default.
• W2082802658 cites W1967917297 @default.
• W2082802658 cites W1981773829 @default.
• W2082802658 cites W1987026350 @default.
• W2082802658 cites W1993800646 @default.
• W2082802658 cites W1996273492 @default.
• W2082802658 cites W2002148380 @default.
• W2082802658 cites W2014250042 @default.
• W2082802658 cites W2017852118 @default.
• W2082802658 cites W2023700648 @default.
• W2082802658 cites W2024652814 @default.
• W2082802658 cites W2028203662 @default.
• W2082802658 cites W2042013850 @default.
• W2082802658 cites W2043325002 @default.
• W2082802658 cites W2061169138 @default.
• W2082802658 cites W2062644687 @default.
• W2082802658 cites W2077341346 @default.
• W2082802658 cites W2078563116 @default.
• W2082802658 cites W2088340243 @default.
• W2082802658 cites W2093321788 @default.
• W2082802658 cites W2101656923 @default.
• W2082802658 cites W2108129627 @default.
• W2082802658 cites W2163485791 @default.
• W2082802658 cites W2212859864 @default.
• W2082802658 cites W2327841955 @default.
• W2082802658 cites W4242721774 @default.
• W2082802658 cites W4246784122 @default.
• W2082802658 doi "https://doi.org/10.3390/toxins6010325" @default.
• W2082802658 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/3920264" @default.
• W2082802658 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/24434906" @default.
• W2082802658 hasPublicationYear "2014" @default.
• W2082802658 type Work @default.
• W2082802658 sameAs 2082802658 @default.
• W2082802658 citedByCount "10" @default.
• W2082802658 countsByYear W20828026582014 @default.
• W2082802658 countsByYear W20828026582015 @default.
• W2082802658 countsByYear W20828026582017 @default.
• W2082802658 countsByYear W20828026582018 @default.
• W2082802658 countsByYear W20828026582019 @default.
• W2082802658 countsByYear W20828026582020 @default.
• W2082802658 countsByYear W20828026582021 @default.
• W2082802658 countsByYear W20828026582022 @default.
• W2082802658 countsByYear W20828026582023 @default.
• W2082802658 crossrefType "journal-article" @default.
• W2082802658 hasAuthorship W2082802658A5004789646 @default.
• W2082802658 hasAuthorship W2082802658A5017963229 @default.
• W2082802658 hasAuthorship W2082802658A5027745355 @default.
• W2082802658 hasAuthorship W2082802658A5067504948 @default.
• W2082802658 hasAuthorship W2082802658A5072671157 @default.
• W2082802658 hasAuthorship W2082802658A5086789687 @default.
• W2082802658 hasBestOaLocation W20828026581 @default.
• W2082802658 hasConcept C104317684 @default.
• W2082802658 hasConcept C119157956 @default.
• W2082802658 hasConcept C161790260 @default.
• W2082802658 hasConcept C178790620 @default.
• W2082802658 hasConcept C181647583 @default.
• W2082802658 hasConcept C185592680 @default.
• W2082802658 hasConcept C21951064 @default.
• W2082802658 hasConcept C2776889654 @default.
• W2082802658 hasConcept C2777367657 @default.
• W2082802658 hasConcept C31903555 @default.
• W2082802658 hasConcept C35753019 @default.
• W2082802658 hasConcept C55493867 @default.
• W2082802658 hasConcept C71240020 @default.
• W2082802658 hasConcept C84699730 @default.
• W2082802658 hasConceptScore W2082802658C104317684 @default.
• W2082802658 hasConceptScore W2082802658C119157956 @default.
• W2082802658 hasConceptScore W2082802658C161790260 @default.
• W2082802658 hasConceptScore W2082802658C178790620 @default.
• W2082802658 hasConceptScore W2082802658C181647583 @default.
• W2082802658 hasConceptScore W2082802658C185592680 @default.
• W2082802658 hasConceptScore W2082802658C21951064 @default.
• W2082802658 hasConceptScore W2082802658C2776889654 @default.
• W2082802658 hasConceptScore W2082802658C2777367657 @default.
• W2082802658 hasConceptScore W2082802658C31903555 @default.
• W2082802658 hasConceptScore W2082802658C35753019 @default.
• W2082802658 hasConceptScore W2082802658C55493867 @default.
• W2082802658 hasConceptScore W2082802658C71240020 @default.
• W2082802658 hasConceptScore W2082802658C84699730 @default.
• W2082802658 hasIssue "1" @default.
• W2082802658 hasLocation W20828026581 @default.
• W2082802658 hasLocation W20828026582 @default.
• W2082802658 hasLocation W20828026583 @default.
• W2082802658 hasLocation W20828026584 @default.
• W2082802658 hasLocation W20828026585 @default.
• W2082802658 hasOpenAccess W2082802658 @default.
• W2082802658 hasPrimaryLocation W20828026581 @default.

• next