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- W2082804930 abstract "By using α-cyanostilbenes as Lewis acids, Lewis acidity scales have been established in ethanolic and methanolic dimethyl sulfoxide containing the appropriate 0.01 M sodium alkoxide and in the system sodium methoxide – methanol. This scale, designated [Formula: see text], describes the ability of the solvent to add an alkoxide ion to an alkene. The [Formula: see text] values range from 11.73 in methanol to 21.74 in 93.27 mole % dimethyl sulfoxide in ethanol.The most acidic indicator used to establish the scale was α-cyano-2,4-dinitrostilbene, with a pK A of 12.73 in dimethyl sulfoxide – methanol. The least acidic was α-cyano-3-trifluoro-methylstilbene, with a pK A of 21.98 in dimethyl sulfoxide – ethanol.The increase in the system's ability to add alkoxide ion to the cyanostilbenes as the dimethyl sulfoxide concentration rises is ascribed chiefly to its effect on the activity of the alkoxide ion. The functions H− and [Formula: see text], unlike their analogues in acid systems (H 0 and H r ), do not diverge greatly as the concentration of the hydroxylic solvent component is decreased." @default.
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- W2082804930 date "1967-10-01" @default.
- W2082804930 modified "2023-09-29" @default.
- W2082804930 title "Addition of alkoxide ions to alkenes. The <i>H</i><sub>R</sub>– scale" @default.
- W2082804930 doi "https://doi.org/10.1139/v67-351" @default.
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