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• W2082867876 abstract "The propene/ethene-[1-13C] copolymerization method has been applied to measure precisely the regioselectivity in propene polymerization of the “simple” MgCl2/TiCl4 catalyst (activated with Al(iBu)3), which can be viewed as the ancestor of all present-day MgCl2-supported industrial catalysts containing Lewis bases as selective modifiers. It has been found that the average content of 2,1-regiomistakes in the polypropylene produced is fairly high (ca. 0.7 mol %), althoughnot unexpectedly, due to the multisite catalyst naturethese are distributed rather nonuniformly throughout the polymer. The difficulty in detecting the 2,1-units, despite their relatively high concentration, in the 13C NMR spectra of homopolymer samples at natural 13C abundance has been traced to their occurrence in a variety of stereochemical environments, which leads to splitting and broadening of the corresponding resonances. The fraction of “dormant” polypropylene chains with a 2,1-last-inserted unit was estimated to be in the 20−50% range. QM calculations of regioselectivity on classical Corradini-type models of epitactic octahedral catalytic Ti species turned out to be in basic agreement with the experiment." @default.
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• W2082867876 date "2003-03-20" @default.
• W2082867876 modified "2023-10-02" @default.
• W2082867876 title "Propene/Ethene-[1-¹³C] Copolymerization as a Tool for Investigating Catalyst Regioselectivity. 2. The MgCl₂/TiCl₄−AlR₃ System" @default.
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• W2082867876 doi "https://doi.org/10.1021/ma034138o" @default.
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