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- W2082881452 startingPage "1083" @default.
- W2082881452 abstract "Two unique lanthanide-based cages [Ln10(L)5(μ2-OH)6(H2O)22](Cl)4⋅7 H2O ([Gd10] and [Dy10]) have been synthesized by using a hydrazone-based ligand H4L (H4L=2,6-bis[(3-methoxysalicylidene)hydrazinecarbonyl]pyridine) and LnCl3⋅x H2O. Structural characterization of [Gd10] reveals an aesthetically pleasing self-assembly of five L4− and ten Gd3+ ions forming a 2×[1×5] rectangular array. The ladder-shaped cage consists of three “rungs” and two “rails” that are occupied by five ligands. Six out of ten gadolinium centers act as rung locks. Further analysis revealed that three chloride ions are encapsulated inside each discrete [Gd10] molecule through hydrogen bonding and other noncovalent interactions. Both the complexes ([Gd10] and [Dy10]) were characterized by powder X-ray diffraction and thermogravimetric analysis, which shows that they are isostructural in nature. Magnetic investigations reveal that [Gd10] is a good candidate for magnetic refrigeration with a significant entropy change (−ΔSm) of 37.4 J kg−1 K−1 for an applied field of 7 T and at 3 K. Whereas [Dy10] shows single-molecule-magnet-like behavior." @default.
- W2082881452 created "2016-06-24" @default.
- W2082881452 creator A5030031955 @default.
- W2082881452 creator A5034067641 @default.
- W2082881452 creator A5035951361 @default.
- W2082881452 creator A5072343015 @default.
- W2082881452 date "2014-02-05" @default.
- W2082881452 modified "2023-10-16" @default.
- W2082881452 title "Synthesis and Characterization of Two Discrete Ln<sub>10</sub>Nanoscopic Ladder-Type Cages: Magnetic Studies Reveal a Significant Cryogenic Magnetocaloric Effect and Slow Magnetic Relaxation" @default.
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- W2082881452 doi "https://doi.org/10.1002/asia.201301619" @default.