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- W2082893114 abstract "Abstract The rates of dissociation of tris(2,2′bipyridine)Fe(II) tris-(1,10-phenanthroline)Fe(II) complexes are lower in D 2 O at 1.0 and 0.01 N HCl, by about 10-20% Gibb's free energy of activation in all the cases is higher in D 2 O. Differencies in enthalpy and entropy of activation are insignificant. However, the variation of rate with the percentage of D 2 O), and the applicability of Barclay-Butler relationship between (ΔH≠) H 2 O → D 2 O and (ΔS≠) H 2 O strongly suggest that differences in rates are primarily due to differences in the free energy of salvation of the initial and transition states in H 2 O and D 2 O." @default.
- W2082893114 created "2016-06-24" @default.
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- W2082893114 date "1980-01-01" @default.
- W2082893114 modified "2023-09-23" @default.
- W2082893114 title "Effect of D2O on the rate and activation parameters of the dissociation of tris(2,2′bipyridine) and tris-(1,10-phenanthroline)Fe(II) complexes in HCl" @default.
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- W2082893114 doi "https://doi.org/10.1016/s0020-1693(00)92017-6" @default.
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