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- W2082907029 abstract "Upon irradiation with a xenon lamp through a Pyrex filter (cut-off below 290nm), aldrin reacted with α -diketones such as glyoxal, methylglyoxal, biacetyl, phenylglyoxal, 1-phenyl-1,2-propanedione and benzil, the former three of which were observed in smog chamber experiments, to give the corresponding epoxide, dieldrin. In the photo-reaction of aldrin with 1-phenyl-1,2-propanedione in quasi-air consisting of 18O2, it appeared that there was 100% incorporation of 18O into dieldrin obtained in high yield. Moreover, in the photo-reactions of olefins such as trans-stilbene, cis-stilbene and cyclohexene with 1-phenyl-1,2-propanedione in air, it was found that both trans-stilbene and cis-stilbene turned to trans-epoxide in moderate yield and cis-epoxide in very poor yield, together with cis-stilbene and trans-stilbene, respectively, and phenanthrene, while cyclohexene did to its epoxide in very poor yield. Based on the fact, a mechanism of the photo-epoxidation is discussed." @default.
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- W2082907029 date "1993-03-01" @default.
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- W2082907029 title "Studies on photochemical reactions of air pollutants. XI. Photochemical epoxidation of aldrin with various α -diketones in air" @default.
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- W2082907029 doi "https://doi.org/10.1016/0045-6535(93)90366-d" @default.
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