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• W2082907623 endingPage "1341" @default.
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• W2082907623 abstract "In 2004, we started to develop a group contribution method aimed at estimating the temperature dependent binary interaction parameters (kij(T)) for the widely used Peng–Robinson equation of state (EOS). This model was called PPR78 (predictive 1978, Peng–Robinson EOS) because it relies on the Peng–Robinson EOS as published by Peng and Robinson in 1978 and because the addition of a group contribution method to estimate the kij makes it predictive. In our previous papers, 14 groups were defined: CH3, CH2, CH, C, CH4 (methane), C2H6 (ethane), CHaro, Caro, Cfused aromatic rings, CH2,cyclic, CHcyclicCcyclic, CO2, N2, and H2S. It was thus possible to estimate the kij for any mixture containing alkanes, aromatics, naphthenes, CO2, N2, and H2S whatever the temperature. In this study, the PPR78 model is extended to systems containing thiols (also called mercaptans). To do so, the sulfhydryl group: –SH was added." @default.
• W2082907623 created "2016-06-24" @default.
• W2082907623 creator A5004799251 @default.
• W2082907623 creator A5008112346 @default.
• W2082907623 creator A5017371723 @default.
• W2082907623 date "2008-09-01" @default.
• W2082907623 modified "2023-10-10" @default.
• W2082907623 title "Addition of the sulfhydryl group (–SH) to the PPR78 model (predictive 1978, Peng–Robinson EOS with temperature dependent kij calculated through a group contribution method)" @default.
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• W2082907623 doi "https://doi.org/10.1016/j.jct.2008.05.013" @default.
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