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• W2082908643 abstract "Novel selective non-hydrogen-bonding DNA base pairs utilizing fluorinated nucleoside analogues have been investigated. Melting studies of DNA duplexes containing 2,3,4,5-tetrafluorobenzene and 4,5,6,7-tetrafluoroindole bases on opposite strands show greater stabilization of the duplex compared with nonfluorinated hydrocarbon controls. Overall, these hydrophobic analogues are destabilizing compared with natural base pairs but are stabilizing compared with natural base mismatches. Such selective pairing may be due to solvent avoidance of these hydrophobic structures, burying their surfaces within the duplex. Our findings suggest that polyfluoroaromatic bases might be employed as a new, selective base-pairing system orthogonal to the natural genetic system." @default.
• W2082908643 created "2016-06-24" @default.
• W2082908643 creator A5029108422 @default.
• W2082908643 creator A5078529502 @default.
• W2082908643 date "2004-02-21" @default.
• W2082908643 modified "2023-10-16" @default.
• W2082908643 title "Selective Pairing of Polyfluorinated DNA Bases" @default.
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• W2082908643 doi "https://doi.org/10.1021/ja039571s" @default.
• W2082908643 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/15012120" @default.
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