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- W2082944489 abstract "The benzylation of thebaine and 6-demethoxythebaine resulted in different product mixtures. Explanations were given for both the observed differences in the ratio of 5β- versus 7-benzyl products and the deviation of the electronic structure of ring C of 7-benzyl products. The acid-catalyzed rearrangement of morphinan-5,8-dienes, 5,6- and 6,7-disubstituted morphinan-6,8-dienes was achieved and mechanistic interpretations for the formation of new, potentially dopamine-active aporphines were provided." @default.
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- W2082944489 date "2008-06-01" @default.
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- W2082944489 title "Benzylation of morphinandienes and new aspects of their acid-catalyzed rearrangement to new aporphines" @default.
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- W2082944489 doi "https://doi.org/10.1016/j.tet.2008.04.069" @default.
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