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• W2082947897 abstract "The redox couples M/M+ of the Group I alkali metals Lithium, Sodium, Potassium, Rubidium and Caesium have been extensively investigated in a room temperature ionic liquid (IL) and compared for the first time. Cyclic voltammetric experiments in the IL N-butyl-N-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide ([C4mpyrr][NTf2]) and subsequent simulation of the data has allowed the determination of the formal potential (Ef0 vs. ferrocene/ferrocenium), standard electrochemical rate constant (k0) and transfer coefficient (α) for each couple in the group. The trend in Ef0 in [C4mpyrr][NTf2] is remarkably similar to the established trend in the common battery electrolyte, propylene carbonate." @default.
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• W2082947897 date "2010-06-01" @default.
• W2082947897 modified "2023-09-27" @default.
• W2082947897 title "The electrode potentials of the Group I alkali metals in the ionic liquid N-butyl-N-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide" @default.
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• W2082947897 doi "https://doi.org/10.1016/j.cplett.2010.04.063" @default.
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